In this study a field‐sampling technique for dissolved hydrogen (H2) in groundwater will be presented which allows the transport of gaseous samples into the laboratory for further analysis. The method consists of transferring the headspace trapped in a gas‐sampling bulb which is continuously purged by groundwater into previously evacuated vials using a gas‐tight syringe. Three transfer steps with preceding evacuation of the vial led to a H2‐recovery of 100 % in laboratory experiments. The method has been applied to determine H2 concentrations in an aquifer contaminated with chlorinated solvents. Tests concerning the effect of different pumping techniques on H2 concentrations revealed that most reliable values were obtained with a bladder pump, while an electrically driven submersible pump generated considerable amounts of hydrogen due to electrochemical interactions with the sampled water. Concentrations of dissolved hydrogen in field and laboratory samples were about two orders of magnitude higher when sampling was performed with the electrically driven submersible pump compared to sampling with the bladder pump and a peristaltic pump. Lab experiments with a Plexiglas reservoir to produce H2‐enriched water were used to study the effect of two tubing materials (PVC, polyamide) on H2 losses. PVC tubing turned out to allow transfer of H2‐enriched water over 25 m without significant losses, while PA‐tubing was not suitable for sampling of H2. 相似文献
The design of a drainage system for a roofing slate quarry was implemented by the enhancement of discharge peak estimation, and the uncertainty inevitably associated with the engineering model was reduced.
The development of a topographical, geological, and vegetation cover database developed from a Geographical Information System (GIS) allowed for the definition of the drainage network for a hydraulic system, along with the calculation of the runoff coefficient. This is applied to the digital model of accumulated flow (DMF) as a weight correction coefficient, using a matrix-based model at 5×5 m resolution. The new digital model of corrected accumulated flow (DMCF) is the result of combining the thematic maps with the map of slope <3%, which was previously created from the slope model. It is demonstrated that this new model allows to apply the “Rational Method” on cartographic units defined by the GIS.
The DMCF is compared with other traditional applications of the Rational Method based on the calculation of the discharge peak considering: (1) the drainage basin as a single watershed or (2) defining an average runoff coefficient in each sub-watershed. Both approaches have bigger discharge peaks than those obtained by the DMCF since the slope, lithology, and vegetation cover have average values, and the runoff coefficient is poorly defined, increasing the uncertainty in the discharge peak. 相似文献
